30 May 2007

Unfortunately, you can't exorcise Maxwell's Demon

So, its a curious thing about ovens. Have you ever noticed?

Let's say you want to heat up a nice tasty batch of chocolate chip cookies. Mmmm mmmm good. So you preheat the oven to 350 degrees, drop the dollops of dough on the non-greased cookie sheet, and pop them in for 10 (gooey) to 12 (crunchy) minutes.

Now, the yumminess before us likely distracts us - at this point - from paying much attention to this matter that I now want to foreground, but let's tarry a moment and ask the question as the cookies cool:

What's going on with the oven?

The oven is cooling too, you see. 350 degrees is hot (that's why you own "oven mitts"), and it takes a while to cool down. In fact, I bet if you went back a half-hour later the inside of the oven would still be at least a little warm to the touch. The heat is dissipating, going elsewhere, but it takes time.

This is thermodynamics in a nutshell.

Here, on the Earth, we are basically moving a more-or-less static amount of heat around. In daily life, it looks like this: You turn on an air conditioner, and the heat in your home is transferred outside. You eat the cookies, and your body chemically burns them to nourish you. When you feel the wind or watch a rainstorm, you are seeing the effects of these temperature differentials at work on a slightly larger scale. On an even larger scale, as the Earth passes through the cold void of space, we lose some of the heat held in the envelope of our atmosphere - an amount that is more or less equivalent to the heat we collect from the thermonuclear reactions of the Sun burning some 93 million miles away. The amount of heat stays pretty much the same, it just moves from place to place, so some areas are temporarily hotter than others.

So our planet is a pretty efficient heat-exchanger, both on the macro scale (we lose heat at about the same amount as the Sun gives us heat) and the micro (Honey, turn on the AC, please).

I watch television so rarely that I am always amazed (agog? apoplectic? anguished?) when I am in a situation when I can spend a few minutes channel surfing. That happened today (I'm staying in a hotel for a work conference) and I happened across a show called Sunset Tan.

Now, on a lot of levels, this show is a study in thermodynamics. It is, if you will, all about moving heat from one place to another. In just the few minutes I watched it, this much was clear.

I was particularly struck by the nine year old girl, brought in by her mother in order to be perfectly tanned for school pictures (the young lady, by the way, got the "cocktail" package - both the bed and the spray - the same one that Britney had gotten earlier that day. "You want the same as Lindsay Lohan, don't you, honey?" asks the mother. Enthusiastic nodding). "This is L.A.," the bronzed twink ex-busboy manager opines, "You've gotta have the darkest tan."

Later the show dissolves into the sort of interpersonal acrimony so resplendent these days in reality TV (the regional manager who bitches out the store managers for not being available "24 hours, seven days a week" even though none of the managers can get the regional manager to return their text messages or phone calls was an especial treat). I have no idea if these people are real, or if this is just subtle parody - but I guess in L.A. there is no way to tell. I mean, in a land of that much sunshine, the fact that one would go to a tanning salon at all sort of begs the question, doesn't it?

The fact that reality TV shows like like American Idol have managed to turn the cold shoulder of rejection and failure into a hot career opportunity is itself a fine illustration of a key thermodynamic principle. In any closed system, unless external energy is added, differences and extremes will eventually equalize and become indistinguishable. Like the Earth upon which American "culture" happens, a state of stability is reached.

This is a roundabout way of admitting that - even though I really want to - I don't think I can, in good conscience, blame American popular culture (as reflected in L.A.-based reality TV) for the problem of global warming. And it breaks my heart that I cannot. But I can't. Reality TV simply moves the heat around. It does not significantly increase our atmospheric temperatures - no more than the hot air in Washington, at any rate.

Instead, I offer this explanation for the current climactic crisis. Not a popular one - in fact, I have not heard it ventured or discussed elsewhere. So it may simply be my kookiness. That being said, however, the theory does attend to these matters of thermodynamics that have preoccupied this little meditation.

Let's return for a moment to that oven with which we started all this, and the time it takes to cool. Like the atmosphere of the Earth, the lining of the oven is a relatively efficient insulator. Left to its own devices, the oven hovers at just-about room temperature. However, when you add a great deal of heat to it, it holds it for a long period of time. When energy is added, the heat dissipates relatively slowly. When you bake the cookies, it takes time for that 350 degrees to go elsewhere.

Now imagine what would happen if you heated that oven to 700 degrees. Then 1400 degrees. Then 2800, and then... you get the idea.

It would take a bit of time for that heat to go somewhere, wouldn't it? And while the temperature difference between the inside and the outside of the oven was equalizing, the room would heat up, and then, from the room, to the outside, and so on. Eventually, you wouldn't notice the heat differences because they would seem relatively equal. We are, after all, dealing with relative temperature extremities. Even 2800 degrees is a somewhat reasonable temperature for the Earth, and so we are, at the end of the day, still only moving heat around a bit, not significantly adding to it within the system.

But what would happen if the temperature in that oven was heated to, say, a couple of million degrees?

Now suddenly we are dealing with a different order of magnitude. This is not a natural temperature for the insulated envelope of atmosphere around the Earth - in fact, the only natural object anywhere near us that generates that kind of heat is the Sun, and it is not actually near us (except in cosmic terms). If you put that kind of energy into your oven, and then opened it, I guarantee you it would really heat your kitchen when you opened the oven door, and likely the whole neighborhood and town, to a temperature that would make things like molten steel seem as innocuous and gentle as, say, a tanning bed.

And because the Earth is, like your oven, a pretty good insulator, the heat you released from you kitchen would linger around a while, heating a greater and greater area as the enthalpic and entropic forces of thermodynamics equalized across the system. The difference being that a couple million degrees goes a lot farther in its effect once equilibrium is again reached.

What I want to point out - and what I haven't heard mentioned in any of the discussions of global warming so far - is that during the middle part of the last century our country (and several others) did exactly what I have just imagined here, with our oven, in the form of nuclear testing in the atmosphere and, later, underground. Not just once or twice, but literally thousands of times.

Though each of the blasts had their own characteristics and differences, one common feature to most, if not all, of them is this: the initial burst of prompt and thermal radiation coming from the fissile core is, at its coolest, about twice the temperature of the surface of the Sun (for some fission bombs it goes as high as three times the Sun).

The United States alone has detonated over a thousand fission devices of various types, not to mention the fissile cores of commercial and military nuclear reactors across the planet. Each of these is generating a glowing spark of new heat into the relatively efficient insulation envelope of the Earth. Not, in other words, simply moving heat around, but creating new heat - vast and unimaginable amounts of it - in isolated but iterated and reiterated instants for almost forty years.

Where on Earth do we foolish mortals (who now wield the hammers of the gods) expect all that heat to go? We have equilibrium with one (one!) comparable heat source that balances the loss of heat in our atmosphere and its over ninety million miles away.

It has always seemed strange to me, having survived the paranoia of the Eighties, that we were so afraid of the effects of nuclear war when we had been, for an entire generation, effectively having one right here in our own country - in Nevada, in New Mexico, in the South Pacific, and high in the stratosphere.

That last one I mentioned - a test called Starfish-Prime - had a measurable effect on the Van Allen radiation belts that interact with the Earth's magnetic poles, in addition to crippling human-made satellites and disrupting communications and electronic equipment across the northern hemisphere. The forces created in nuclear blasts - the electromagnetic and ionizing - are well-known to linger and bounce through the Earth's atmosphere and magnetic fields for years after a blast. Why should we expect the thermal effects to be any different?

They aren't any different. The great actuarial table of thermodynamics is against us. In a closed system (like the relatively efficient insulator of the Earth's atmosphere) heat stays around, becoming general and ubiquitous, until it bleeds away. Slowly. And if you add insane amounts of heat to such a system - even if it doesn't seem to heat everything at once (because these things take time) it will. Don't just trust me: I am merely quoting the experts.

At the turn of the century James Clerk Maxwell asked what would happen to an imaginary closed system if you could put a demon into it - one that would be able to sort out the high-energy molecules of a gas from the low energy ones. The demon would be able to sort out energy problems without creating more energy problems - would be able, in other words, to deal with heat without creating more heat. A wonderful, if wholly imaginary, solution (and one that would make those in the present administration, perhaps, blush with hope): salvation without sacrifice; an instantaneous reversal of our slow and dedicated penchant for destruction (self- and otherwise).

In times such as these, such a creature might be useful. Some might argue we should find such a demon and make a deal with it. Others might observe that it may well have been such a deal that got us in the present mess in the first place.

Perhaps it is already too late for those sorts of eleventh-hour bargains. Too late, at any rate, for a "quick fix" that doesn't involve some very, very hard sacrifices. It's a devilish reality, even compared to the treacheries of an L.A. tanning salon.

So that's my theory. You can disagree with my conclusions, and I am happy to debate it over a plate of chocolate chip cookies (I prefer gooey). Though I rather think, from here forward, we might be wise to eschew debate in favor of something more effective. Like prayer.